According to the principle of dimensional homogeneity, the dimensions of each terms of a dimensional equation on both sides are the same.
So, dimension of b and V will be same, [b]=[V]
And dimension of V2a and P will be same, [V2a]=[P]
From above two relations, we have [b2a]=[P]
∴[ab2]=[P]1=[ML−1T−2]−1
Thus, [M−1L1T2] is the dimension of compressibility.