Concept - Those compounds which are more acidic than H2CO3 can gives effervescence of CO2 with aq. NaHCO3.
Release CO2↑ gas with aq. NaHCO 3
⇒[ A.S. ]Comp. >[ A.S. ]H2CO3
→ Option 1,2 and 3 gives effervescence of CO2 gas with NaHCO3
→ Option (4) Not gives CO2 gas with NaHCO3.