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JEE Main 2016 — Organic Chemistry

Chemistry Organic Chemistry questions from JEE Main 2016.

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21 Organic Chemistry Questions from 2016

The absolute configuration of ![JEE Main 2016 Chemistry, General Organic Chemistry — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/General_Organic_Chemistry/648b5a64417cc3fb48d66006/question_1__q_648b5a64417cc3fb48d66006__cdn-question-pool.getmarks.app__image4-3a9e5e06-86a3-43a7-97bf-9c85b53f3332__4f97018a54_final_ppt_sync.png) is:

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The product of the reaction give below is: ![JEE Main 2016 Chemistry, Haloalkanes and Haloarenes — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a64417cc3fb48d6600f/question_1__q_648b5a64417cc3fb48d6600f__cdn-question-pool.getmarks.app__9b208f5f-7e15-4d8e-9924-b706d4733cd7-quesst__0f609f1af1_final_ppt_sync.png)

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Bouveault-Blanc reduction reaction involves:

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The distillation technique most suited for separating glycerol from spent - lye in the soap industry is:

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$2$- chloro - $2$ - methylpentane on reaction with sodium methoxide in methanol yields: (i) ![JEE Main 2016 Chemistry, Haloalkanes and Haloarenes — question figure 1](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a64417cc3fb48d66014/question_1__q_648b5a64417cc3fb48d66014__cdn-question-pool.getmarks.app__image26-9f76e861-1a2c-4ae1-a78a-0c87afd0ee14__2609f22761_final_ppt_sync.png) (ii) ![JEE Main 2016 Chemistry, Haloalkanes and Haloarenes — question figure 2](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a64417cc3fb48d66014/question_2__q_648b5a64417cc3fb48d66014__cdn-question-pool.getmarks.app__image27-288ab881-f90e-49d1-8615-d2039db73687__2a9d071842_final_ppt_sync.png) (iii) ![JEE Main 2016 Chemistry, Haloalkanes and Haloarenes — question figure 3](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a64417cc3fb48d66014/question_3__q_648b5a64417cc3fb48d66014__cdn-question-pool.getmarks.app__image28-31e7583f-5ca6-4813-a89b-4933cb7c6b94__cf5859a82d_final_ppt_sync.png)

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In the Hoffmann bromamide degradation reaction, the number of moles of $\mathrm{NaOH}$ and $B{r}_{2}$ used per mole of amine produced are:

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$5L$ of an alkane requires $25L$ of oxygen for its complete combustion. If all volumes are measured at constant temperature and pressure, the alkane is

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Fluorination of an aromatic ring is easily accomplished by treating a diazonium salt with $HB{F}_{4}$. Which of the following conditions is correct about this reaction?

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The correct statement about the synthesis of erythritol $(C{(C{H}_{2}OH)}_{4})$ used in the preparation of PETN is

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The test to distinguish primary, secondary and tertiary amines is:

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Thiol group is present in:

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Bromination of cyclohexene under conditions given below yields: ![JEE Main 2016 Chemistry, Haloalkanes and Haloarenes — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a65417cc3fb48d660cc/question_1__q_648b5a65417cc3fb48d660cc__cdn-question-pool.getmarks.app__image9-a63f092e-4360-42a3-8a30-ccfcebb2e5e2__55869a2909_final_ppt_sync.jpg)

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The hydrocarbon with seven carbon atoms containing a neopentyl and a vinyl group is:

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The gas evolved on heating $C{H}_{3}MgBr$ in methanol is:

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The $N$ which contribute least to the basicity of the compound is : ![JEE Main 2016 Chemistry, Amines — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Amines/648b5a65417cc3fb48d660b9/question_1__q_648b5a65417cc3fb48d660b9__cdn-question-pool.getmarks.app__image2-c55cf25a-5711-41a2-9e7a-497edbd0197d__7c6551cdae_final_ppt_sync.jpg)

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Observation of "Rhumann's purple" is a confirmatory test for the presence of:

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Which one of the following reagents is not suitable for the elimination reaction? ![JEE Main 2016 Chemistry, Haloalkanes and Haloarenes — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a65417cc3fb48d660bb/question_1__q_648b5a65417cc3fb48d660bb__cdn-question-pool.getmarks.app__image3-70fcda5d-32da-48b9-b599-5e4090177024__1cadc64b05_final_ppt_sync.jpg)

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Sodium extract is heated with concentrated $HN{O}_{3}$ before testing for halogens because :

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Consider the following sequence for aspartic acid: ![JEE Main 2016 Chemistry, Biomolecules — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Biomolecules/648b5a65417cc3fb48d66065/question_1__q_648b5a65417cc3fb48d66065__cdn-question-pool.getmarks.app__29eb5e05-77fc-4035-9742-657fd75270eb-lppp__e55661f3b4_final_ppt_sync.jpg) The pH (Isoelectric point) of aspartic acid is:

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Consider the reaction sequence below: ![JEE Main 2016 Chemistry, Hydrocarbons — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Hydrocarbons/648b5a65417cc3fb48d660ce/question_1__q_648b5a65417cc3fb48d660ce__cdn-question-pool.getmarks.app__image16-97a713e9-62a2-45b3-8b2a-9460ad823162__d65a57bce7_final_ppt_sync.jpg) X is :

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The reaction of propene with$\mathrm{HOCl}$ $(C{l}_{2}+{H}_{2}O)$ proceeds through the intermediate:

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