(C) Only primary amine gives carbyl amine test (D) Benzene sulphonyl chloride Ph−SO2Cl Hinsberg reagent (E) Tertiary amine do not react with Ph−SO2Cl So correct options are (B) and (D) only
Identify correct statements : (A) Primary amines do not give diazonium salts when treated with NaNO2 in acidic condition. (B) Aliphatic and aromatic primary amines on heating with CHCl3 and ethanolic KOH form carbylamines. (C) Secondary and tertiary amines also give carbylamine test. (D) Benzenesulfonyl chloride is known as Hinsberg's reagent. (E) Tertiary amines reacts with benzenesulfonyl chloride very easily. Choose the correct answer from the options given below :
Held on 28 Jan 2025 · Verified 6 Jul 2026.
(A) and (B) only
(D) and (E) only
(B) and (D) only
(B) and (C) only
Sign in to track your attempts and accuracy.
Sign in to keep a private note on this question. Nothing you write is ever public.
Consider the following reaction sequence  Compound $(\mathrm{y})$ develops characteristic colour with neutral $\mathrm{FeCl}_{3}$ solution. Identify the INCORRECT statement from the following for the above sequence.
Given below are two statements: Statement I: Benzene is nitrated to give nitrobenzene, which on further treatment with $\mathrm{CH}_{3} \mathrm{COCl} / \mathrm{AlCl}_{3}$ will give  Statement II: $-\mathrm{NO}_{2}$ group is a $m$-directing, and deactivating group. In the light of the above statements, choose the most appropriate answer from the options given below
Given below are two statements: Statement I: $\left(\mathrm{CH}_{3}\right)_{3} \stackrel{\oplus}{\mathrm{C}}$ is more stable than $\stackrel{\oplus}{\mathrm{C}} \mathrm{H}_{3}$ as nine hyperconjugation interactions are possible in $\left(\mathrm{CH}_{3}\right)_{3} \stackrel{\oplus}{\mathrm{C}}$. Statement II: $\stackrel{\oplus}{\mathrm{C}} \mathrm{H}_{3}$ is less stable than $\left(\mathrm{CH}_{3}\right)_{3} \stackrel{\oplus}{\mathrm{C}}$ as only three hyperconjugation interactions are possible in $\stackrel{\oplus}{\mathrm{C}} \mathrm{H}_{3}$. In the light of the above statements, choose the correct answer from the options given below
Which of the following reactions is an example of Wurtz reaction?
A hydroxy compound $(\mathrm{X})$ with molar mass $122 \mathrm{~g} \mathrm{~mol}^{-1}$ is acetylated with acetic anhydride, using a large excess of the reagent ensuring complete acetylation of all hydroxyl groups. The product obtained has a molar mass of $290 \mathrm{~g} \mathrm{~mol}^{-1}$. The number of hydroxyl groups present in compound (X) is:
Work through every JEE Main Organic Chemistry PYQ, year by year.