Given:
Compound is optically active ⇒ contains chiral carbon/Nitrogen.
Compound liberates N2 gas with HNO2⇒ It is primary amine
Compound reacts with PhSO2Cl and the product is soluble in KOH - It is a primary amine.
Option (A) and (D) are primary amines. But only option (D) satisfy all the above conditions.



