Which of the following has the shortest C-Cl bond?

The correct order of the rate of reaction of the following reactants with nucleophile by SN1 mechanism is: (Given : Structure I and II are rigid) 

Identify the incorrect statements.  Choose the correct answer from the options given below:

For the following Friedel Craft's alkylation reaction, which of the statements are correct?  A. Major product is n-propyl benzene. B. iso-propyl carbocation intermediate is also generated. C. Multiple substitution is inevitable. D. Introducing electron-donating substituent on benzene will not produce any alkyl benzene. Choose the correct answer from the options given below:

Match the LIST-I with LIST-II <table class="pyq-table"><tbody><tr><th>List-I (Reaction)</th><th>List-II (Mechanism)</th></tr><tr><td>A. Williamson Synthesis</td><td>I. Electrophilic addition</td></tr><tr><td>B. Friedel Craft Reaction</td><td>II. Free radical substitution</td></tr><tr><td>C. Bromination of vinyl benzene</td><td>III. Nucleophilic substitution</td></tr><tr><td>D. Chlorination of toluene in light</td><td>IV. Electrophilic substitution</td></tr></tbody></table> Choose the correct answer from the options given below:

Consider the following reactions sequence  When the product (P) is subjected to Carius analysis using $AgNO_3$, $1.0$ g of the product (P) will produce _______ g of the precipitate of AgBr. (Nearest Integer) (Given: molar mass in g mol$^{-1}$ C : 12, H : 1, O : 16, N : 14, Br : 80, Ag : 108)