For capillary rise, the height of liquid in a tube is given by: h=ρgr2Tcosθ, where T is surface tension and r is the tube radius.
For two liquids with equal density and contact angles:
h1=ρgr12T1cosθ and h2=ρgr22T2cosθ
Taking the ratio: h2h1=T2T1×r1r2
Since r1>r2, we have r1r2<1. The capillary rise is inversely proportional to tube radius, so the smaller radius tube will have greater height. Since the liquids are measured to have heights h1 and h2 with r1>r2, and they have the same density, the empirical relation shows that both liquids rise to different heights inversely proportional to their radii. For liquids with the same density measured in different tubes, if the heights and radii satisfy the capillary rise equation, the surface tensions must be equal: T1=T2, and h1<h2 since r1>r2.