Work done is given by, W=Fscosθ, where θ is the angle between the force and the displacement.
case(A): Direction of force and displacement both are in the same direction and hence work done will be positive. Hence, wrong.
case(B): Direction of force and displacement both are in the opposite direction and hence work done will be negative. Hence, correct.
case(C): Direction of force and displacement both are in the opposite direction and hence work done will be negative. Hence, wrong.
case(D): Direction of force and displacement both are in the same direction and hence work done will be positive. Hence, wrong.
case(E): Direction of force and displacement both are in the opposite direction and hence work done will be negative. Hence, correct.