Let the tension in the string is T.
Applying the condition of equilibrium in the vertical direction,
Tcos(45∘)=100
⇒2T=100 ...(1)
In the horizontal direction,
Tsin(45∘)=F
⇒2T=F
Put the value of T from equation (1),
⇒F=100N
So, the horizontal force applied on the rope will be 100N.