The given process Li2+(g)→Li3+(g)+e− represents the ionization of the hydrogen-like ion Li2+ from its ground state.
The ionization energy for a hydrogen-like species is given by the formula:
IE=IEH×Z2
For Li2+, the atomic number Z=3.
Given the ionization energy of the hydrogen atom IEH=2.18×10−18 J atom−1.
Substituting the values:
IE=2.18×10−18×(3)2
IE=2.18×10−18×9
IE=19.62×10−18 J atom−1
IE=1.962×10−17 J atom−1
Answer: 1.962×10−17