The dissociation reaction of the weak electrolyte AxBy is:
AxBy⇌xAy++yBx−
Initial concentrations:
c00
Equilibrium concentrations:
c(1−α)cxαcyα
The dissociation constant K is given by:
K=[AxBy][Ay+]x[Bx−]y
K=c(1−α)(cxα)x(cyα)y
K=c(1−α)cx+yxxyyαx+y
K=1−αcx+y−1xxyyαx+y
For a weak electrolyte, the degree of dissociation α is very small, so 1−α≈1.
K=cx+y−1xxyyαx+y
Solving for α:
αx+y=cx+y−1xxyyK
α=(cx+y−1xxyyK)x+y1
Answer: (cx+y−1xxyyK)x+y1