For a first order reaction, the rate constant k is given by:
k=t1ln[A]t[A]0
Using the data at t=20 min:
k=201ln0.000650.6500=201ln1000=203ln10
Using the data at t=x min:
k=x1ln0.06500.6500=x1ln10
Equating the two expressions for k:
203ln10=x1ln10
203=x1
x=320=6.66...
Rounding to the nearest integer, we get x=7.
Answer: 7