The rise in temperature of neutralization reaction will be maximum for maximum number of moles of strong acid and strong base neutralized and lower volume of final solution. (3) HCl+NaOH→NaCl+H2O mmol 3030 Final volume of solution =60 mL Option (1) and (2) have weak acids and in option (4) only 20 mmol of HCl will be neutralized with 70 mL final volume.