$\begin{aligned}
& \mathrm{N}_2(\mathrm{g})+3 \mathrm{H}_2(\mathrm{g}) \rightarrow 2 \mathrm{NH}_3 \
& \Delta \mathrm{H}^{\circ}=-\mathrm{ve} \
& \Delta \mathrm{~S}^{\circ}=-\mathrm{ve}
\end{aligned}$
(As gaseous moles decreases).
(1) As temperature increases T−ΔHR0, decreases
(2) ΔG∘=−RTlnKeq
RlnKeq=− TΔG0
(on increasing temperature in exothermic reaction Keq decreases)
ΔH∘ and ΔS∘ are almost constant with temperature.



