Skip to main content

JEE Main 2025 Chemistry, Thermodynamics (C) — question figure Two vessels A and B are connected via stopcock. The vessel A is filled with a gas at a…

JEE Main 2025 — Chemistry Physical Chemistry

2025mcqmedium

JEE Main 2025 Chemistry, Thermodynamics (C) — question figure

Two vessels A and B are connected via stopcock. The vessel A is filled with a gas at a certain pressure. The entire assembly is immersed in water and is allowed to come to thermal equilibrium with water. After opening the stopcock the gas from vessel A expands into vessel B and no change in temperature is observed in the thermometer. Which of the following statement is true?

Official previous-year question

Held on 2 Apr 2025 · Verified 6 Jul 2026.

Options

  1. A

    dw≠0d w \neq 0dw=0

  2. B

    dq≠0\mathrm{dq} \neq 0dq=0

  3. C

    dU≠0\mathrm{dU} \neq 0dU=0

  4. D

    The pressure in the vessel BBB before opening the stopcock is zero.

Did you get this right?

Sign in to track your attempts and accuracy.

Your note

Sign in to keep a private note on this question. Nothing you write is ever public.

JEE Main Physical Chemistry in other years

More JEE Main Physical Chemistry questions

What is the ratio of wave number of first line (lowest energy line) of Balmer series of H atomic spectrum to first line of its Brackett series?

2026medium

![JEE Main 2026 Chemistry, Structure of Atom — question figure 1](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Structure_of_Atom/6983c1ae8bfdbb24356397c7/question_1__q_6983c1ae8bfdbb24356397c7__cdn-question-pool.getmarks.app__28S1_q_64_1__80fd8624a7_final_ppt_sync.png) ![JEE Main 2026 Chemistry, Structure of Atom — question figure 2](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Structure_of_Atom/6983c1ae8bfdbb24356397c7/question_2__q_6983c1ae8bfdbb24356397c7__cdn-question-pool.getmarks.app__28S1_q_64_2__04a1587871_final_ppt_sync.png) Which of the following point in Figure 2 most accurately represents the nodal surface as shown in Figure 1?

2026medium

At 298 K, the mole percentage of $\mathrm{N}_{2}(\mathrm{~g})$ in air is $80 \%$. Water is in equilibrium with air at a pressure of 10 atm. What is the mole fraction of $\mathrm{N}_{2}(\mathrm{~g})$ in water at 298 K ? ($\mathrm{K}_{\mathrm{H}}$ for $\mathrm{N}_{2}$ is $6.5 \times 10^{7} \mathrm{~mm} \mathrm{Hg}$)

2026medium

Electricity is passed through an acidic solution of $\mathrm{Cu}^{2+}$ till all the $\mathrm{Cu}^{2+}$ was exhausted, leading to the deposition of 300 mg of Cu metal. However, a current of 600 mA was continued to pass through the same solution for another 28 minutes by keeping the total volume of the solution fixed at 200 mL. The total volume of oxygen evolved at STP during the entire process is $\_\_\_\_$ mL. (Nearest integer) [Given: $\mathrm{Cu}^{2+}(\mathrm{aq})+2 \mathrm{e}^{-} \rightarrow \mathrm{Cu}(\mathrm{s}) \mathrm{E}_{\text {red }}^{\mathrm{o}}=+0.34 \mathrm{~V}$ $\mathrm{O}_{2}(\mathrm{~g})+4 \mathrm{H}^{+}+4 \mathrm{e}^{-} \rightarrow 2 \mathrm{H}_{2} \mathrm{O} \mathrm{E}_{\text {red }}^{\mathrm{o}}=+1.23 \mathrm{~V}$ Molar mass of $\mathrm{Cu}=63.54 \mathrm{~g} \mathrm{~mol}^{-1}$ Molar mass of $\mathrm{O}_{2}=32 \mathrm{~g} \mathrm{~mol}^{-1}$ Faraday Constant $=96500 \mathrm{C} \mathrm{mol}^{-1}$ Molar volume at $\mathrm{STP}=22.4 \mathrm{~L}$]

2026hard

Arrange the following resultant mixtures in increasing order of their pH values A. $10$ mL $0.2$ M Ca(OH)$_2$ + $25$ mL $0.1$ M HCl B. $10$ mL $0.01$ M H$_2$SO$_4$ + $10$ mL $0.01$ M Ca(OH)$_2$ C. $10$ mL $0.1$ M H$_2$SO$_4$ + $10$ mL $0.1$ M KOH Choose the correct answer from the options given below:

2026medium

Other Chemistry topics for JEE Main

Keep practicing Physical Chemistry

Work through every JEE Main Physical Chemistry PYQ, year by year.

Browse all Chemistry topics