The minimum amount of energy necessary to start the emission of electrons from a metal's surface is known as its work function. The work function is the minimum amount of energy required to remove an electron from a metal's surface to infinity.
Energy of incident photon =λhc
=400×10−96.6×10−34×3×108J
=400×10−9×1.6×10−96.6×10−34×3×108eV
=3.1eV
If radiation energy is greater than work function of metal, then metal show photo electric effect.
∴Li,Na and K will show photoelectric effect.