
k,=2.0
m=0.5m
ΔTr=km
Tintial=272K
n=0.1mol
V=1dm3
Pgas=VnRT=10.1×0.08×272
After releasing piston P1V1=P2V2
2.176×1=1×V2
V3=2.176dm3
JEE Main 2020 — Chemistry Physical Chemistry
A cylinder containing an ideal gas ( 0.1mol of 1.0dm3 ) is in thermal equilibrium with a large volume of 0.5 molal aqueous solution of ethylene glycol at its freezing point. If the stoppers S1 and S2 (as shown in the figure) are suddenly withdrawn, the volume of the gas in litres after equilibrium is achieved will be _____________.
(Given, Kf(water)=2.0Kkgmol−1,R=0.08dm3atmK−1mol−1)

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