For cyclic process: ΔU=0⇒q=−w
For isothermal process: ΔU=0⇒q=−w
For adiabatic process: q=0⇒ΔU=w
For isochoric process: w=0⇒ΔU=q
JEE Main 2019 — Chemistry Physical Chemistry
Which one of the following equations does not correctly represent the first law of thermodynamics for the given processes involving an ideal gas? (Assume non- expansion work is zero)
Held on 8 Apr 2019 · Verified 6 Jul 2026.
Isochoric process : ΔU=q
Isochoric process : q=–w
Cyclic process : q=–w
Adiabatic process : ΔU=−w
Sign in to track your attempts and accuracy.
Sign in to keep a private note on this question. Nothing you write is ever public.
What is the ratio of wave number of first line (lowest energy line) of Balmer series of H atomic spectrum to first line of its Brackett series?
  Which of the following point in Figure 2 most accurately represents the nodal surface as shown in Figure 1?
At 298 K, the mole percentage of $\mathrm{N}_{2}(\mathrm{~g})$ in air is $80 \%$. Water is in equilibrium with air at a pressure of 10 atm. What is the mole fraction of $\mathrm{N}_{2}(\mathrm{~g})$ in water at 298 K ? ($\mathrm{K}_{\mathrm{H}}$ for $\mathrm{N}_{2}$ is $6.5 \times 10^{7} \mathrm{~mm} \mathrm{Hg}$)
Electricity is passed through an acidic solution of $\mathrm{Cu}^{2+}$ till all the $\mathrm{Cu}^{2+}$ was exhausted, leading to the deposition of 300 mg of Cu metal. However, a current of 600 mA was continued to pass through the same solution for another 28 minutes by keeping the total volume of the solution fixed at 200 mL. The total volume of oxygen evolved at STP during the entire process is $\_\_\_\_$ mL. (Nearest integer) [Given: $\mathrm{Cu}^{2+}(\mathrm{aq})+2 \mathrm{e}^{-} \rightarrow \mathrm{Cu}(\mathrm{s}) \mathrm{E}_{\text {red }}^{\mathrm{o}}=+0.34 \mathrm{~V}$ $\mathrm{O}_{2}(\mathrm{~g})+4 \mathrm{H}^{+}+4 \mathrm{e}^{-} \rightarrow 2 \mathrm{H}_{2} \mathrm{O} \mathrm{E}_{\text {red }}^{\mathrm{o}}=+1.23 \mathrm{~V}$ Molar mass of $\mathrm{Cu}=63.54 \mathrm{~g} \mathrm{~mol}^{-1}$ Molar mass of $\mathrm{O}_{2}=32 \mathrm{~g} \mathrm{~mol}^{-1}$ Faraday Constant $=96500 \mathrm{C} \mathrm{mol}^{-1}$ Molar volume at $\mathrm{STP}=22.4 \mathrm{~L}$]
Arrange the following resultant mixtures in increasing order of their pH values A. $10$ mL $0.2$ M Ca(OH)$_2$ + $25$ mL $0.1$ M HCl B. $10$ mL $0.01$ M H$_2$SO$_4$ + $10$ mL $0.01$ M Ca(OH)$_2$ C. $10$ mL $0.1$ M H$_2$SO$_4$ + $10$ mL $0.1$ M KOH Choose the correct answer from the options given below:
Work through every JEE Main Physical Chemistry PYQ, year by year.