As per (n+l) rule electrons fill first in that orbital which have least (n+l) value.
When (n+l) values are same, then electron fills that orbital which have lowest n value.
when n=6 as per (n+l) rule when n=6
ns subshell ⇒6+0=6
(n−1)d subshell ⇒5+2=7
(n−2)f subshell ⇒4+3=7
np subshell ⇒6+1=7
ns,(n−2)f,(n−1)d,np
(n+l)values⇒7,7,7
nvalue⇒4,5,6