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Choose the correct tests with respective observations. (A) CuSO_4 (acidified with acetic acid) + K_4 [ Fe( CN)_6 ] → Chocolate brown precipitate. (B)…

JEE Main 2025 — Chemistry Inorganic Chemistry

2025mcqhard

Choose the correct tests with respective observations.

(A) CuSO4\mathrm{CuSO}_4CuSO4​ (acidified with acetic acid) +K4[Fe(CN)6]→+ \mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right] \rightarrow+K4​[Fe(CN)6​]→ Chocolate brown precipitate.

(B) FeCl3+K4[Fe(CN)6]→\mathrm{FeCl}_3+\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right] \rightarrowFeCl3​+K4​[Fe(CN)6​]→ Prussian blue precipitate.

(C) ZnCl2+K4[Fe(CN)6]\mathrm{ZnCl}_2+\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]ZnCl2​+K4​[Fe(CN)6​], neutralised with NH4OH\mathrm{NH}_4 \mathrm{OH}NH4​OH →\rightarrow→ White or bluish white precipitate.

(D) MgCl2+K4[Fe(CN)6]→\mathrm{MgCl}_2+\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right] \rightarrowMgCl2​+K4​[Fe(CN)6​]→ Blue precipitate.

(E) BaCl2+K4[Fe(CN)6]\mathrm{BaCl}_2+\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]BaCl2​+K4​[Fe(CN)6​], neutralised with NaOH →\rightarrow→ White precipitate.

Choose the correct answer from the options given below :

Official previous-year question

Held on 2 Apr 2025 · Verified 6 Jul 2026.

Options

  1. A

    A, D and E only

  2. B

    B, D and E only

  3. C

    A, B and C only

  4. D

    C, D and E only

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