According to Statement I,
On addition of dimethylglyoxime (DMG) to nickel ion solution and on adding little bit of ammonia to make solution basic, it will give a red precipitate. This is a very specific test for nickel +2 cation.
The reaction is as follows,
Ni2++NH4OH+dmg→

2 hydrogen bonded chelatesare formed.
According to Statement II,
IIIFe4 II[Fe(CN)6]3
Prussian Blue
IN this complex Fe is at +3as well as+2oxidation state. Where ionisation sphere is Fe3+ and coordination sphere has Fe2+
Hence option A is the answer..