Number of atoms is calculated as the product of the number of moles, atomicity, and Avogadro's number (NA).
For A: Moles of O2 = 322=161 mol. Atomicity of O2 is 2.
Number of atoms = 161×2×NA=81NA
For B: Moles of SO2 = 644=161 mol. Atomicity of SO2 is 3.
Number of atoms = 161×3×NA=163NA
For C: Moles of O2 at STP = 224001400=161 mol. Atomicity of O2 is 2.
Number of atoms = 161×2×NA=81NA
For D: Moles of He at STP = 22.40.05=4481 mol. Atomicity of He is 1.
Number of atoms = 4481×1×NA=4481NA
For E: Moles of H2 = 0.0625=161 mol. Atomicity of H2 is 2.
Number of atoms = 161×2×NA=81NA
Comparing the number of atoms, A, C, and E contain the same number of atoms.
Answer: A, C and E only