The radius of the n-th Bohr orbit for a hydrogen-like species is given by the formula:
rn=a0Zn2
where a0 is the Bohr radius of the hydrogen atom (52.9 pm), n is the principal quantum number, and Z is the atomic number.
Given rn=70.53 pm, we can write:
70.53=52.9×Zn2
Zn2=52.970.53=1.333=34
Checking the given options:
For Li2+ and n=3, Z=3⇒Zn2=39=3
For He+ and n=3, Z=2⇒Zn2=29=4.5
For He+ and n=2, Z=2⇒Zn2=24=2
For Li2+ and n=2, Z=3⇒Zn2=34
The ratio matches for Li2+ and n=2.
Answer: Li2+,2