Fe2+(aq)+Ag+(aq)→Fe3+(aq)+Ag(s) 
$\begin{aligned}
& \Delta \mathrm{G}3^0=\Delta \mathrm{G}1^0+\Delta \mathrm{G}2^0 \
& -3 \mathrm{F}(-\mathrm{z})=-2 \mathrm{F}(-\mathrm{y})+\Delta \mathrm{G}2{ }^0 \
& \Delta \mathrm{G}2^0=3 \mathrm{Fz}-2 \mathrm{Fy}
\end{aligned}Also\Delta \mathrm{G}2^0=-\mathrm{nFE}{\mathrm{Fe}^{+2} / \mathrm{Fe}^{t^{43}}}^0\begin{aligned}
& 3 \mathrm{Fz}-2 \mathrm{Fy}=-1 \mathrm{~F}\left(\mathrm{E}{\mathrm{Fe}^{t^2} / \mathrm{Fe}^{43}}^0\right) \
& \mathrm{E}{\mathrm{Fe}^{2+2} / \mathrm{Fe}^{t^3}}^0=2 \mathrm{y}-3 \mathrm{z}
\end{aligned}\mathrm{E}{\text {Cell }}^0forreactionwillbe\begin{aligned}
& \mathrm{E}{\mathrm{Ag}^{+} / \mathrm{Ag}}^0+\mathrm{E}{\mathrm{Fe}^{t^2 / \mathrm{Fe}}}^{03} \
& =\mathrm{x}+2 \mathrm{y}-3 \mathrm{z}
\end{aligned}$