Given Molar mass of Ag:108gmol−1
Equal equivalents of substances deposited or liberated when some quantity of electricity passed through circuite in the electrolysis cell.
Equivalents of silver deposited= Equivalents of O2 liberated.
Let x gm silver displaced,
(Molar volume of gas at STP =22.4L )
Number equivalents of a substance = The number of moles of substance × Valence factor of that substance
108x×1=22.45.6×4,x=108gm.