Skip to main content

A litre of buffer solution contains 0.1 mole of each of NH_3 and NH_4 Cl. On the addition of 0.02 mole of HCl by dissolving gaseous HCl, the pH of…

JEE Main 2023 — Chemistry Physical Chemistry

2023integerhard

A litre of buffer solution contains 0.10.10.1 mole of each of NH3{\mathrm{NH}}_{3}NH3​ and NH4Cl{\mathrm{NH}}_{4}\mathrm{Cl}NH4​Cl. On the addition of 0.020.020.02 mole of HCl\mathrm{HCl}HCl by dissolving gaseous HCl\mathrm{HCl}HCl, the pH\mathrm{pH}pH of the solution is found to be _____\times {10}^{-3} (Nearest integer)

Given: pKb(NH3)=4.745{\mathrm{pK}}_{b}({\mathrm{NH}}_{3})=4.745pKb​(NH3​)=4.745

log2=0.301\mathrm{log}2=0.301log2=0.301

log3=0.477\mathrm{log}3=0.477log3=0.477

T=298K]T=298K]T=298K]

Official previous-year question

Held on 25 Jan 2023 · Verified 6 Jul 2026.

Did you get this right?

Sign in to track your attempts and accuracy.

Your note

Sign in to keep a private note on this question. Nothing you write is ever public.

JEE Main Physical Chemistry in other years

More JEE Main Physical Chemistry questions

What is the ratio of wave number of first line (lowest energy line) of Balmer series of H atomic spectrum to first line of its Brackett series?

2026medium

![JEE Main 2026 Chemistry, Structure of Atom — question figure 1](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Structure_of_Atom/6983c1ae8bfdbb24356397c7/question_1__q_6983c1ae8bfdbb24356397c7__cdn-question-pool.getmarks.app__28S1_q_64_1__80fd8624a7_final_ppt_sync.png) ![JEE Main 2026 Chemistry, Structure of Atom — question figure 2](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Structure_of_Atom/6983c1ae8bfdbb24356397c7/question_2__q_6983c1ae8bfdbb24356397c7__cdn-question-pool.getmarks.app__28S1_q_64_2__04a1587871_final_ppt_sync.png) Which of the following point in Figure 2 most accurately represents the nodal surface as shown in Figure 1?

2026medium

At 298 K, the mole percentage of $\mathrm{N}_{2}(\mathrm{~g})$ in air is $80 \%$. Water is in equilibrium with air at a pressure of 10 atm. What is the mole fraction of $\mathrm{N}_{2}(\mathrm{~g})$ in water at 298 K ? ($\mathrm{K}_{\mathrm{H}}$ for $\mathrm{N}_{2}$ is $6.5 \times 10^{7} \mathrm{~mm} \mathrm{Hg}$)

2026medium

Electricity is passed through an acidic solution of $\mathrm{Cu}^{2+}$ till all the $\mathrm{Cu}^{2+}$ was exhausted, leading to the deposition of 300 mg of Cu metal. However, a current of 600 mA was continued to pass through the same solution for another 28 minutes by keeping the total volume of the solution fixed at 200 mL. The total volume of oxygen evolved at STP during the entire process is $\_\_\_\_$ mL. (Nearest integer) [Given: $\mathrm{Cu}^{2+}(\mathrm{aq})+2 \mathrm{e}^{-} \rightarrow \mathrm{Cu}(\mathrm{s}) \mathrm{E}_{\text {red }}^{\mathrm{o}}=+0.34 \mathrm{~V}$ $\mathrm{O}_{2}(\mathrm{~g})+4 \mathrm{H}^{+}+4 \mathrm{e}^{-} \rightarrow 2 \mathrm{H}_{2} \mathrm{O} \mathrm{E}_{\text {red }}^{\mathrm{o}}=+1.23 \mathrm{~V}$ Molar mass of $\mathrm{Cu}=63.54 \mathrm{~g} \mathrm{~mol}^{-1}$ Molar mass of $\mathrm{O}_{2}=32 \mathrm{~g} \mathrm{~mol}^{-1}$ Faraday Constant $=96500 \mathrm{C} \mathrm{mol}^{-1}$ Molar volume at $\mathrm{STP}=22.4 \mathrm{~L}$]

2026hard

Arrange the following resultant mixtures in increasing order of their pH values A. $10$ mL $0.2$ M Ca(OH)$_2$ + $25$ mL $0.1$ M HCl B. $10$ mL $0.01$ M H$_2$SO$_4$ + $10$ mL $0.01$ M Ca(OH)$_2$ C. $10$ mL $0.1$ M H$_2$SO$_4$ + $10$ mL $0.1$ M KOH Choose the correct answer from the options given below:

2026medium

Other Chemistry topics for JEE Main

Keep practicing Physical Chemistry

Work through every JEE Main Physical Chemistry PYQ, year by year.

Browse all Chemistry topics