2CH3COOH1−α⇌(CH3COOH)22α
i=1−2α
ΔTf=i×Kf×m
0.45=i×5.12×60×200.2×1000
i=0.527=1−2α
⇒α=0.946 or 94.6
JEE Main 2017 — Chemistry Physical Chemistry
The freezing point of benzene decreases by 0.45∘C on adding 0.2g of acetic acid to 20g of benzene. If acetic acid associates to form a dimer in benzene, then what is the percentage association of acetic acid in benzene?
(Kfforbenzene=5.12Kkgmol−1)
Held on 2 Apr 2017 · Verified 6 Jul 2026.
80.4
74.6
94.6
64.6
Sign in to track your attempts and accuracy.
Sign in to keep a private note on this question. Nothing you write is ever public.
Arrange the following isothermal processes in order of the magnitude of the work ($p - V$) involved between states $1$ and $2$. A. Expansion in single stage $w_A$ B. Expansion in multi stages $w_B$ C. Compression in single stage $w_C$ D. Compression in multi stages $w_D$ Choose the correct option.
Identify the correct statements from the following: A. Heisenberg uncertainty principle is applicable to electrons. B. The size of $2p_x$ orbital is less than the size of $3p_x$ orbital. C. The energy of $2s$ orbital of H atom is equal to the energy of $2s$ orbital of Li. D. The electronic configuration of Cr is $[\text{Ar}] 3d^5 4s^1$ Choose the correct answer from the options given below:
80 mL of a hydrocarbon on mixing with 264 mL of oxygen in a closed U-tube undergoes complete combustion. The residual gases after cooling to 273 K occupy 224 mL. When the system is treated with KOH solution, the volume decreases to 64 mL. The formula of the hydrocarbon is :
$19.5$ g of fluoro acetic acid (molar mass $= 78$ g mol$^{-1}$) is dissolved in $500$ g of water at $298$ K. The depression in the freezing point of water was $1°$C. What is $K_a$ of fluoro acetic acid? (For water, $K_f = 1.86$ K kg mol$^{-1}$). Assume molarity and molality to have same values.
$M_3 A_2$ is a sparingly soluble salt of molar mass $y$ g mol$^{-1}$ and solubility $x$ g L$^{-1}$. The ratio of the molar concentration of the anion ($A^{3-}$) to the solubility product of the salt is
Work through every JEE Main Physical Chemistry PYQ, year by year.