Irreversible process
W=PΔV=nRT
100mol2H2O2(l)⇌2H2O(l)+50molO2(g)
∴ 100molH2O2 on decomposition will give 50molO2
=50×8.3×300
=124500J
=124.50kJ
JEE Main 2016 — Chemistry Physical Chemistry
If100mole of H2O2 decompose at 1bar and 300K, the work is done (kJ) by one mole of O2(g) as it expands against 1bar pressure is:
2H2O2(l)⇌2H2O(l)+O2(g)
(R=8.3JK−1mol−1)
Held on 10 Apr 2016 · Verified 6 Jul 2026.
124.50
249.00
498.00
62.25
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