XBenzene=51.5=0.3
XToluene=53.5=0.7
According to Raoult's Law
P=xAP∘A+xBP∘B
Ptotal=0.3×74.7+0.7×22.3
=22.41+15.61=38.02
≈38Torr
By Dalton's law to vapour phase
Mole fraction of a gas in a mixture of gas=Total no.moles in the mixturePartial pressure of gas(P1)
XBenzene′(Vapourphase)=380.3×74.7=3822.41
=0.589