Statement I describes the Hoffmann bromamide degradation reaction. When benzamide (C6H5CONH2) is heated with bromine in an ethanolic solution of sodium hydroxide, it produces aniline (C6H5NH2), not benzylamine. Thus, Statement I is false.
Statement II describes the nitration of aniline. Direct nitration of aniline with HNO3/H2SO4 yields a mixture of p-nitroaniline (51%), m-nitroaniline (47%), and o-nitroaniline (2%). The significant formation of the meta derivative is due to the protonation of aniline in the strongly acidic medium to form the anilinium ion, which is meta-directing. Since 47%>2%, m-nitroaniline is produced in a higher amount than o-nitroaniline. Thus, Statement II is true.
Answer: Statement I is false but Statement II is true