Statement 1: B.P. of chloroform =334K
B.P. of aniline =457K
thus can be seprated of simple distillation.
Statement 2 : Mixture of aniline and water seprated by simple distillation.
A suitable method for separating a mixture of aniline and chloro form would be steam distillation. Steam distillation is the process used to separate aromatic compound from a mixture because of their temperature sensitivity. Therefore, steam distillation is an ideal method for their separation