K2Cr2O7 in acidic medium acts as a strong oxidizing agent. It changes its colour from orange (Cr2O72−) to green (Cr3+) when it reacts with a reducing agent.
We need to identify the set in which all species can act as reducing agents (i.e., they can be oxidized to a higher oxidation state).
In option (A), Fe2+ oxidizes to Fe3+, Sn2+ oxidizes to Sn4+, I− oxidizes to I2, and S2− oxidizes to S. All of these are reducing agents.
In option (B), Fe3+ is already in its maximum stable oxidation state and cannot be oxidized further.
In option (C), Sn4+ cannot be oxidized further.
In option (D), Fe3+, SO42−, and Sn4+ cannot be oxidized further.
Thus, only the species in option (A) will change the orange colour of K2Cr2O7.
Answer: Fe2+,Sn2+,I−,S2−