The spin-only magnetic moment is given by μ=n(n+2) BM, where n is the number of unpaired electrons.
For μ>3.0 BM, n must be ≥3 (since for n=2, μ=8≈2.83 BM and for n=3, μ=15≈3.87 BM).
Electronic configurations and unpaired electrons (n) in high spin octahedral complexes:
| Metal Ion | Configuration | n | μ (BM) |
| Co2+ | [Ar]3d7 | 3 | 3.87 |
| Ni2+ | [Ar]3d8 | 2 | 2.83 |
| Fe2+ | [Ar]3d6 | 4 | 4.90 |
| V3+ | [Ar]3d2 | 2 | 2.83 |
| Ti2+ | [Ar]3d2 | 2 | 2.83 |
The metal ions with μ>3.0 BM are Co2+ (n=3) and Fe2+ (n=4).
The sum of unpaired electrons for these ions is 3+4=7.