In Statement I, the bond angle of F2O is 103∘, H2O is 104.5∘, and Cl2O is 110.9∘. The increasing order of bond angle is F2O<H2O<Cl2O. In F2O, the high electronegativity of fluorine shifts the bond pairs towards fluorine, decreasing bond pair-bond pair repulsion and thus decreasing the bond angle. In Cl2O, steric hindrance between the large chlorine atoms increases the bond angle. Thus, Statement I is true.
In Statement II, SiF4 is a covalent compound (it is a gas at room temperature), whereas SnF4 and PbF4 are ionic solids. Thus, Statement II is false.
Answer: Statement I is true but Statement II is false