$\begin{aligned}
& \mathrm{PF}_5: 5 \sigma+0 \ell \mathrm{p} \rightarrow \mathrm{sp}^3 \mathrm{~d} \
& \mathrm{SF}_6: 6 \sigma+0 \ell \mathrm{p} \rightarrow \mathrm{sp}^3 \mathrm{~d}^2 \
& \mathrm{Ni}(\mathrm{CO})_4: \mathrm{Ni} \rightarrow 0
\end{aligned}$
In presence of ligand field :-

[PtCl4]2−:Pt→+2
In presence of ligand field :-
