Inter-molecular structure of Boric acid(H3BO3) in solid phase:

Boric acid has strong hydrogen bonding as we can see in the above figure, while BF3 does not. Therefore boric acid is solid.
JEE Main 2023 — Chemistry Inorganic Chemistry
Boric acid in solid, whereas BF3 is gas at room temperature because of
Held on 30 Jan 2023 · Verified 6 Jul 2026.
Strong ionic bond in Boric acid
Strong van der Waal's interaction in Boric acid
Strong hydrogen bond in Boric acid
Strong covalent bond in BF3
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