Option 1: Mn+2[Ar]3d5,Cr+[Ar]3d5
Cr is expected to have the highest second ionization enthalpy as after removal of 4s electrons, the electrons will be removed from d-orbital. Cr+ have stable half-filled d-orbital with maximum spin multiplicity.
Option −2Ni+2[Ar]3d8,Cu+[Ar]3d10
Option −3Fe+2[Ar]3d6,Co+[Ar]3d74s1
Option −4V+2[Ar]3d3,Cr+[Ar]3d5