Pb(NO3)2⟶ΔPbO+2NO2
N2 gas is constituent of air and it produces ammonia gas (basic nature) after reacting with H2 gas.
NH4NO2,(NH4)2Cr2O7andNaN3give nitrogen gas on heating but lead nitrate doesn't give nitrogen gas so it will be answer.
NH4NO2⟶ΔN2+2H2O
(NH4)2Cr2O7⟶ΔN2+Cr2O3+H2O
NaN3⟶300∘C3N2+2Na