Given, magnetic moment of di-oxygen species= 1.73 B . M . =1.73B.M. = 1.73 B . M .
We know, magnetic moment = n ( n + 2 ) =\sqrt{ \text{n}( \text{n}+2) } = n ( n + 2 ) , where n = n= n = number of unpaired electrons
1.73 = n ( n + 2 ) 1.73=\sqrt{ \text{n}( \text{n}+2) } 1.73 = n ( n + 2 )
n = 1 \text{n}=1 n = 1
So, species should contain one unpaired electron.
Let us check by electronic configuration of each species
O 2 = σ 1 s 2 σ ∗ 1 s 2 σ 2 s 2 σ ∗ 2 s 2 σ 2 p 2 z π 2 p 2 x = π 2 p 2 y π ∗ 2 p 1 x = π ∗ 2 p 1 y O 2 + = σ 1 s 2 σ ∗ 1 s 2 σ 2 s 2 σ ∗ 2 s 2 σ 2 p 2 z π 2 p 2 x = π 2 p 2 y π ∗ 2 p 1 x = π ∗ 2 p 0 y O 2 − = σ 1 s 2 σ ∗ 1 s 2 σ 2 s 2 σ ∗ 2 s 2 σ 2 p 2 z π 2 p 2 x = π 2 p 2 y π ∗ 2 p 2 x = π ∗ 2 p 1 y {O}_{2}=\sigma 1{s}^{2}{\sigma }^{*}1{s}^{2}\sigma 2{s}^{2}{\sigma }^{*}2{s}^{2}\sigma 2{{p}^{2}}_{z}\pi 2{{p}^{2}}_{x}=\pi 2{{p}^{2}}_{y}{\pi }^{*}2{{p}^{1}}_{x}={\pi }^{*}2{{p}^{1}}_{y} {{O}_{2}}^{+}=\sigma 1{s}^{2}{\sigma }^{*}1{s}^{2}\sigma 2{s}^{2}{\sigma }^{*}2{s}^{2}\sigma 2{{p}^{2}}_{z}\pi 2{{p}^{2}}_{x}=\pi 2{{p}^{2}}_{y}{\pi }^{*}2{{p}^{1}}_{x}={\pi }^{*}2{{p}^{0}}_{y} {{O}_{2}}^{-}=\sigma 1{s}^{2}{\sigma }^{*}1{s}^{2}\sigma 2{s}^{2}{\sigma }^{*}2{s}^{2}\sigma 2{{p}^{2}}_{z}\pi 2{{p}^{2}}_{x}=\pi 2{{p}^{2}}_{y}{\pi }^{*}2{{p}^{2}}_{x}={\pi }^{*}2{{p}^{1}}_{y} O 2 = σ 1 s 2 σ ∗ 1 s 2 σ 2 s 2 σ ∗ 2 s 2 σ 2 p 2 z π 2 p 2 x = π 2 p 2 y π ∗ 2 p 1 x = π ∗ 2 p 1 y O 2 + = σ 1 s 2 σ ∗ 1 s 2 σ 2 s 2 σ ∗ 2 s 2 σ 2 p 2 z π 2 p 2 x = π 2 p 2 y π ∗ 2 p 1 x = π ∗ 2 p 0 y O 2 − = σ 1 s 2 σ ∗ 1 s 2 σ 2 s 2 σ ∗ 2 s 2 σ 2 p 2 z π 2 p 2 x = π 2 p 2 y π ∗ 2 p 2 x = π ∗ 2 p 1 y
As clear by above electronic configurations that, O 2 {O}_{2} O 2 has two unpaired electrons and {{O}_{2}}^{-}&{{O}_{2}}^{+} Each has only one unpaired electron; hence magnetic moment of {{O}_{2}}^{+}&{{O}_{2}}^{-} is 1.73 B . M . 1.73B.M. 1.73 B . M .