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Among the statements (a)-(d) , the incorrect ones are: (a) Octahedral Co(III) complexes with strong field ligands have very high magnetic moments (b)…

JEE Main 2020 — Chemistry Inorganic Chemistry

2020mcqmedium

Among the statements (a)−(d)(a)-(d)(a)−(d) , the incorrect ones are:

(a)(a)(a) Octahedral Co(III)Co(III)Co(III) complexes with strong field ligands have very high magnetic moments

(b)(b)(b) When Δ0<P{\Delta }_{0}<PΔ0​<P , the d-electron configuration of Co(III)Co(III)Co(III) in an octahedral complex is teg4eg2{t}_{eg}^{4}{e}_{g}^{2}teg4​eg2​

(c)(c)(c) Wavelength of light absorbed by [Co(en)3]3+{[Co{(en)}_{3}]}^{3+}[Co(en)3​]3+ is lower than that of [CoF6]3−{[{CoF}_{6}]}^{3-}[CoF6​]3−

(d)(d)(d) If the Δ0{\Delta }_{0}Δ0​ for an octahedral complex of Co(III)Co(III)Co(III) is 18,000cm−118,000c{m}^{-1}18,000cm−1, the Δt{\Delta }_{t}Δt​ for its tetrahedral complex with the same ligand will be 16,000cm−116,000c{m}^{-1}16,000cm−1.

Official previous-year question

Held on 7 Jan 2020 · Verified 6 Jul 2026.

Options

  1. A

    (a)(a)(a) and (d)(d)(d) only

  2. B

    (c)(c)(c) and (d)(d)(d) only

  3. C

    (a)(a)(a) and (b)(b)(b) only

  4. D

    (b)(b)(b) and (c)(c)(c) only

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