27Co3+ has 24 Electrons i.e 6 electrons in inner 3d orbital of central metal ion for diamagnetic behaviour these d6 Electrons have to be paired and due to pairing two inner d-orbitals get empty and hybridisation is d2sp3.

JEE Main 2014 — Chemistry Inorganic Chemistry
An octahedral complex of Co3+ is diamagnetic. The hybridisation involved in the formation of the complex is :
Held on 9 Apr 2014 · Verified 6 Jul 2026.
dsp2
d2sp3
dsp3d
sp3d2
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