[Fe(CN)6]3− has magnetic moment of a single unpaired electron whereas [FeF6]3− has a magnetic moment of five unpaired electrons. [CoF6]3− is paramagnetic with four unpaired electrons while [Co(C2O4)3]3 is diamagnetic. This anomaly is explained by valence bond theory in terms of formation of inner and outer orbital coordination entities. [Co(C2O4)3]3− is an inner orbital complexes having d2sp3 hybridization.
Which of the following is diamagnetic ?
JEE Main 2013 — Chemistry Inorganic Chemistry
Which of the following is diamagnetic ?
Held on 22 Apr 2013 · Verified 6 Jul 2026.
Options
- A
[Fe(CN)6]3−
- B
[Co(ox)3]3−
- C
[FeF6]3−
- D
[CoF6]3−
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