option itself is the reason
JEE Main 2009 — Chemistry Inorganic Chemistry
The bond dissociation energy of B−F in BF3 is 646 kJ mol −1 whereas that of C−F in CF4 is 515 kJ mol −1. The correct reason for higher B-F bond dissociation energy as compared to that of C - F is :
Held on 30 Apr 2009 · Verified 6 Jul 2026.
smaller size of B-atom as compared to that of C-atom
stronger σ bond between B and F in BF3 as compared to that between C and F in CF4
significant pπ−pπ interaction between B and F in BF3 whereas there is no possibility of such interaction between C and F in CF4.
lower degree of pπ−pπ interaction between B and F in BF3 than that between C and F in CF4.
Sign in to track your attempts and accuracy.
Sign in to keep a private note on this question. Nothing you write is ever public.
It is noticed that $\mathrm{Pb}^{2+}$ is more stable than $\mathrm{Pb}^{4+}$ but $\mathrm{Sn}^{2+}$ is less stable than $\mathrm{Sn}^{4+}$. Observe the following reactions. $\mathrm{PbO}_{2}+\mathrm{Pb} \rightarrow 2 \mathrm{PbO} ; \Delta_{\mathrm{r}} \mathrm{G}^{\circ}(1)$ $\mathrm{SnO}_{2}+\mathrm{Sn} \rightarrow 2 \mathrm{SnO} ; \Delta_{\mathrm{r}} \mathrm{G}^{\circ}(2)$ Identify the correct set from the following
In a period, the first ionisation enthalpy of the element at extreme left and the negative electron gain enthalpy of the extreme right element, except noble gases, are respectively.
First and second ionization enthalpies of lithium are $520$ kJ mol$^{-1}$ and $7297$ kJ mol$^{-1}$ respectively. Energy required to convert $3.5$ mg lithium (g) into $\text{Li}^{2+}$(g) $[\text{Li(g)} \rightarrow \text{Li}^{2+}\text{(g)}]$ is _______ kJ mol$^{-1}$. (nearest integer) [Molar mass of Li $= 7$ g mol$^{-1}$]
Which of the following elements has the highest electronegativity?
On heating a mixture of common salt and $\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}$ in equal amount along with concentrated $\mathrm{H}_{2} \mathrm{SO}_{4}$ in a test tube, a gas is evolved. Formula of the gas evolved and oxidation state of the central metal atom in the gas respectively are:
Work through every JEE Main Inorganic Chemistry PYQ, year by year.