The surface charge density of a closed surface area having charge Q is given by σ= Area Charge =AQ or Q=σA Thus, the charges on sphere P and Q having same charge density as shown in the figure below is given by 
QP=σ×4πR2=4πσR2 and QQ=σ×4π(2R)2=16πσR2 when they are brought in contact with each other, the total charge will be Qt==QP+QQ4πσR2+16πσR2 [From Eq. (i) and (ii)] =20πσR2 In connection of two charged conducting bodies, the potential will become same on both, i.e. 4π∈0RQP=4πϵ02RQQ⇒RQP=2RQQ⇒QQQP=21 So, the charges on the sphere P and Q after separation will be distributed as ⇒QP′=31Qt and QQ′=32Qt After separation, the new surface charge densities on P and Q will be σP= Area QP′ and σQ= Area QQ′=31 Area Qt=314πR220πσR2=35σ=32 Area Qt=32×4π(2R)220πσR2=32×45σ=65σ