Using Rydberg formula,
λ1=R(nf21−ni21), where, R is Rydberg constant and n is quantum number.
For first line of Lyman series
λ1=R(1−41)=R(43)
⇒λ=3R4...(1)
For 3rd line of Paschen series
λ31=R(321−621)=9R×43
For 2nd line of Balmer series
λ21=R(221−421)=4R×43
Thus, aλ=λ3−λ2=R12−3R16=3R20
Putting equation (1)
a(3R4)=3R20⇒a=5