The electric potential at center O is the scalar sum of contributions from all 5 charges.
Each charge is equidistant from center, so V=5cdotrkq=4πϵ0r5q.
The electric field is a vector sum of field vectors from all 5 charges.
Due to 5-fold rotational symmetry of a regular pentagon, the 5 field vectors point radially outward from center, equally spaced at 72° angles.
The vector sum of 5 equally spaced unit vectors is zero, so E=0.
