Charge and charge density on both isolated metallic solid spheres are show below.

Let the charges and the charge densities on both the spheres after connected by thin conducting wire be Q1′,Q2′,σandσ′ as shown below.

Once connected, charge on both the spheres will redistribute such that potentials at the surface of both spheres is the same.
∴RkQ1′=2RkQ2′
⇒4πϵ0RQ1′=4πϵ0(2R)Q2′
∴Q2′=2Q1′
Using charge conservation,
Q1′+Q2′=Q1+Q2
∴2Q2′+Q2′=20πR2σ
23Q2′=20πR2σ
∴4π(2R)2Q2′=32×16πR220πR2σ
∴σσ′=65