Let the volume of each vessel be V.
Initially, both vessels are at pressure P1=90 kPa and temperature T1=400 K.
Total number of moles initially is given by:
ni=RT1P1V+RT1P1V=RT12P1V
Finally, the temperature of the first vessel is T1=400 K and the second vessel is T2=500 K. Let the final pressure be Pf.
Total number of moles finally is given by:
nf=RT1PfV+RT2PfV
Since the total number of moles remains constant, ni=nf:
RT12P1V=RT1PfV+RT2PfV
Substituting the given values:
4002×90=400Pf+500Pf
400180=Pf(4001+5001)
400180=Pf(20005+4)
400180=Pf(20009)
Pf=400×9180×2000
Pf=20×5=100 kPa
Answer: 100