Statement I is true because for an ideal gas, the change in internal energy is given by ΔU=nCvΔT. Using Mayer's relation Cp−Cv=R and the ratio of specific heats γ=CvCp, we can write Cv=γ−1R. Substituting this, we get ΔU=γ−1nR(Tf−Ti).
Statement II is true because according to the law of equipartition of energy, the molar heat capacity at constant volume is Cv=2fR and at constant pressure is Cp=(2f+1)R. Therefore, γ=CvCp=1+f2.
Statement II does not explain Statement I, as Statement I is derived purely from macroscopic thermodynamic relations (Mayer's relation) and is independent of the microscopic concept of degrees of freedom.
Hence, both statements are true but Statement II is NOT the correct explanation of Statement I.
Answer: Both A and R are true but R is NOT the correct explanation of A