The given relation between pressure and volume is:
P=Po(1+(VVo)2)−1
For sample A, the initial volume is VA=Vo. Substituting this into the given relation, the initial pressure PA is:
PA=Po(1+(VoVo)2)−1=2Po
Using the ideal gas equation PV=nRT for n=2 moles, the initial temperature TA is:
TA=nRPAVA=2R(2Po)Vo=4RPoVo
For sample B, the initial volume is VB=3Vo. Substituting this into the relation, the initial pressure PB is:
PB=Po(1+(3VoVo)2)−1=Po(1+91)−1=109Po
The initial temperature TB for n=2 moles is:
TB=nRPBVB=2R(109Po)(3Vo)=20R27PoVo
The difference in the initial temperatures of the two samples is:
TB−TA=20R27PoVo−4RPoVo
TB−TA=20R27PoVo−5PoVo=20R22PoVo=10R11PoVo
Answer: 10R11PoVo